New PDF release: Actinide Nanoparticle Research

By Horst Geckeis, Thomas Rabung, Thorsten Schäfer (auth.), Stepan N. Kalmykov, Melissa A. Denecke (eds.)

ISBN-10: 3642114318

ISBN-13: 9783642114311

This is the 1st e-book to hide actinide nano learn. it's of curiosity either for basic study into the chemistry and physics of f-block components in addition to for utilized researchers resembling these learning the long term defense of nuclear waste disposal and constructing remediation innovations. The authors conceal very important problems with the formation of actinide nano-particles, their homes and constitution, environmental habit of colloids and nanoparticles relating to the secure disposal of nuclear wastes, modeling and complex equipment of characterization on the nano-scale.

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Extra resources for Actinide Nanoparticle Research

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Labeled humate complexes with Boom Clay, the major part of Am becomes almost instantaneously dissociated and retained on the clay. Only a small fraction persists to migrate along with the mobile organic matter at even long contact times. Dissociation of Am(III) from this fraction was fit to a first order kinetic model with a rate of 8 Â 10À8 sÀ1 only (Maes et al. 2006). This value lies in-line with dissociation rates determined by Bryan et al. (2006) and King et al. (2001) [summarized and collected in Bryan et al.

Part 1: Batch sorption and time- 28 H. Geckeis et al. resolved laser fluorescence spectroscopy experiments. Geochimica Et Cosmochimica Acta 69 (23), 5393–5402. Rajagopalan R. and Tien C. (1976) Trajectory analysis of deep-bed filtration with the sphere-incell porous media model. AIChE Journal 22, 523–533. Roberts K. , Santschi P. , Leppard G. , and West M. M. (2004) Characterization of organicrich colloids from surface and ground waters at the actinide-contaminated Rocky Flats Environmental Technology Site (RFETS), Colorado, USA.

5 mol/L) taken from the Swedish underground rock laboratory (URL), colloids can be even a sink for actinide migration due to their agglomeration and subsequent sedimentation (Bouby et al. 2008). 6, I ¼ 10–3 mol/L) ground water of the Swiss URL at the GTS, however, high mobility for bentonite colloids has been reported in various in situ migration studies. The colloid-borne lanthanides and actinides Tb(III), Am(III) and Th(IV), Pu(IV) were found to be transported in dipole experiments over distances up to 5 m with high colloid and actinide recoveries ranging from 30 to 80% (Geckeis et al.

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Actinide Nanoparticle Research by Horst Geckeis, Thomas Rabung, Thorsten Schäfer (auth.), Stepan N. Kalmykov, Melissa A. Denecke (eds.)

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